Better is subject to a lot of interpretation, isn't it? Urethane SS is great as a color coat imo, especially against shrinkage and chipping, but if the film build of the color coat is too high, it will chip just like a basecoat job will. I guess I prefer SS for solids and basecoat for metallics, but that may be because I am a bit scared of the metallic screwing up on me, just not enough of a finesse painter to make it happen 100% of the time.
Can't say I know much about Centari, except that I had a job that was cleared with 780S peel like a snake starting at 3 years old. So that soured me on it, but SS Centari was probably pretty good. I started using Delstar or Deltron SS with DAU82 on top after the peeler incident, but haven't used either for over 15 years.