To some extent. If the surface is too hot it can actually “burn” the epoxy and the epoxy will dry real crumbly (experienced this myself).
If you want epoxy to spray better and make it as fool proof as possible then you would actually heat the can to 90 degrees on a hot plate. Myself, especially on a cool day, will induce my epoxy and set the mix cup out on the asphalt driveway in the sun to get real warm.
The complicated chemistry of the epoxy comes down to the alcohols, which is where the issues come from with cold sensitivity. It is not like urethane chemistry and in my numerous conversations with Barry over the last 14 years I’ve gathered that his epoxy with its alcohol is also a very unique formulation.
Also, the “open window” is different than curing or the cure time. Epoxy takes about 90 days to fully cure.